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Technical Paper

Development of a Methodology to Separate Thermal from Oil Aging of a Catalyst Using a Gasoline-Fueled Burner System

2003-03-03
2003-01-0663
Typically, an engine/dynamometer thermal aging cycle contains combinations of elevated catalyst inlet temperatures, chemical reaction-induced thermal excursions (simulating misfire events), and average air/fuel ratio's (AFR's) to create a condition that accelerates the aging of the test part. In theory, thermal aging is predominantly a function of the time at an exposure temperature. Therefore, if a burner system can be used to simulate the exhaust AFR and catalyst inlet and bed temperature profile generated by an engine running an accelerated aging cycle, then a catalyst should thermally age the same when exposed to either exhaust stream. This paper describes the results of a study that examined the aging difference between six like catalysts aged using the Rapid Aging Test (RAT) cycle (an accelerated thermal aging cycle). Three catalysts were aged using a gasoline-fueled engine aging stand; the other three were aged using a computer controlled burner system.
Technical Paper

FTP and US06 Performance of Advanced High Cell Density Metallic Substrates as a Function of Varying Air/Fuel Modulation

2003-03-03
2003-01-0819
The influence of catalyst volume, cell density and precious metal loading on the catalyst efficiency were investigated to design a low cost catalyst system. In a first experiment the specific loading was kept constant for a 500cpsi and a 900cpsi substrate. In a second experiment the palladium loading was reduced on the 900cpsi substrate and the same PM loading was applied to a 1200cpsi substrate with lower volume. Finally the loading was further reduced for the 1200cpsi substrate. The following parameters were studied after aging: Catalyst performance of standard cell density compared to high cell density technology Light-off performance and catalyst efficiency as a function of Palladium loading and substrate cell density Catalyst efficiency as a function of AFR biasing The performance of the aged catalysts was investigated in a lambda sweep test and in light-off tests at an engine bench.
Technical Paper

Study of Modern Application Strategies for Catalytic Aftertreatment Demonstrated on a Production V6 Engine

2001-03-05
2001-01-0925
A study was performed to develop optimum design strategies for a production V6 engine to maximize catalyst performance at minimum pressure loss and at minimum cost. Test results for an advanced system, designed to meet future emission limits on a production V6 vehicle, are presented based on FTP testing. The on-line pressure loss and temperature data serves to explain the functioning of the catalyst.
Technical Paper

Phased Air/Fuel Ratio Perturbation - A Fuel Control Technique for Improved Catalyst Efficiency

2000-03-06
2000-01-0891
This paper describes the results of a study that examined the mechanism of phased perturbation as an emissions control technique. Phased perturbation involves independently controlling the fuel delivered to each bank of a dual bank engine (or each cylinder of a single manifold engine), which allows the two banks to have an adjustable, relative Air/Fuel (A/F) perturbation phase-shift from one another. The phase shifted exhaust is then recombined to achieve a near stoichiometric mixture prior to entering a single underbody catalyst. Phase shifting the exhaust Air/Fuel ratio creates a situation in which both rich exhaust constituents (unburnt hydrocarbons and carbon monoxide) and lean exhaust constituents (oxygen and oxides of nitrogen) arrive at the catalyst at the same time. The results of the study showed that phased perturbation produced a significant effect on A/F control and catalyst THC, CO, and NOx efficiency.
Technical Paper

Nonroad Engine Activity Analysis and Transient Cycle Generation

1999-09-14
1999-01-2800
The United States Environmental Protection Agency (EPA) has initiated Phase I of a regulatory program to control exhaust emissions of nonroad diesel engines over 37 kW. Central to any emissions regulation is the test procedure, which must include an appropriate test cycle. Based on actual in-use speed and estimated torque data collected from an agricultural tractor, a backhoe-loader, and a crawler tractor, three duty cycles were developed. Using an iterative process, comparison of chi-square statistical data was used to identify representative microtrips, segments of engine operation gathered during performance of selected activities. Representative microtrips for specific activities for a particular nonroad application were “strung” together to make up a test cycle. Before accepting the test cycle, data for the cycle was compared to statistical data used to characterize the raw data in an effort to validate that the cycle was representative of the raw data.
Technical Paper

ERIC - A System to Modify Vehicle Emissions Through Computer Controlled Signal Interception

1999-03-01
1999-01-0773
A computer controlled system capable of intercepting and performing closed-loop control of a vehicle subsystem during targeted modes of operation was developed. The system has been given the acronym ERIC, for Emissions Reduction Intercept and Control system. This study was prompted by the need for the ability to modify engine controls through targeted modes of operation, without altering the majority of engine operation, to assist in the integration of exhaust aftertreatment and engine systems. The general concept and approach for applying the ERIC method, and application of the system to perform targeted, mode-activated EGR control intercept on a 1997 Ford Crown Victoria, are described in this paper. Data are presented that demonstrate how the problem mode was identified, targeted, mapped, and modified. FTP-75 test data are presented to show the impact of this particular application.
Technical Paper

Using Advanced Emission Control Systems to Demonstrate LEV II ULEV on Light-Duty Gasoline Vehicles

1999-03-01
1999-01-0774
A program to demonstrate the performance of advanced emission control systems in light of the California LEV II light-duty vehicle standards and the EPA's consideration of Tier II emission standards was conducted. Two passenger cars and one light-duty pick-up truck were selected for testing, modification, and emission system performance tuning. All vehicles were 1997 Federal Tier I compliant. The advanced emission control technologies evaluated in this program included advanced three-way catalysts, high cell density substrates, and advanced thermally insulated exhaust components. Using these engine-aged advanced emission control technologies and modified stock engine control strategies (control modifications were made using an ERIC computer intercept/control system), each of the three test vehicles demonstrated FTP emission levels below the proposed California LEV II 193,000 km (120,000 mile) ULEV levels.
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